| Governor | Term |
| Padre Diego Luis de San Vitores(did not have actual title) | 1668-1672 |
| Captain Francisco de Irrisarri y Vinar |
1676-1680 |
| Don Jose de Quiroga |
1680-1681 |
| Captain Antonio de Saravia |
1681-1684 |
| Captain Damian de Esplana | 1684-1693 |
| Don Jose de Quiroga | 1693-1700 |
| Major Francisco Madraso y Asiam |
1700-1704 |
| Major Antonio Villamor y Vadillo | 1704-1709 |
| Lieutenant General Juan Antonio Pimentel | 1709-1720 |
| Captain Luis Antonio Sanchez de Tagle | 1720-1725 |
| Captain Juan Ojeda | 1725-1725 |
| General Manuel Arguelles Valda | 1725-1730 |
| Major Pedro Laso de la Vega | 1730-1734 |
| General of the Fleet Francisco Cardenas Pacheco | 1734-1740 |
| Major Miguel Fernando de Cardenas | 1740-1746 |
| Captain Domingo Gomez de la Sierra | 1746-1749 |
| Navy Lieutenant Enrique de Olavide y Michelena | 1749-1756 |
| General Andres del Barrio y Rabago | 1756-1759 |
| Navy Lieutenant Jose de Soroa | 1759-1768 |
| Major Mariano Tobias | 1771-1774 |
| Major Antonio Apicada | 1774-1776 |
| Captain Felipe de Cera | 1776-1786 |
| Lieutenant Colonel Jose Arlegue y Leon | 1786-1794 |
| Lieutenant Colonel Manuel Muro | 1794-1802 |
| Captain Vicente Blanco | 1802-1806 |
| Captain Alejandro Parreno | 1806-1812 |
| Lieutenant Colonel Jose de Medinilla y Pineda | 1812-1822 |
| Captain Jose Montilla | 1822-1823 |
| Captain Jose Ganga Herrero | 1823-1826 |
| Lieutenant Colonel Jose de Medinilla y Pineda | 1826-1831 |
| Captain Francisco Ramon de Villalobos | 1831-1837 |
| Lieutenant Colonel Jose Casillas Salazar | 1837-1843 |
| Major Gregorio Santa Maria | 1843-1848 |
| Lieutenant Colonel Pablo Perez | 1848-1855 |
| Lieutenant Colonel Felipe Maria dela Corte y Ruano Calderon |
1855-1866 |
| Lieutenant Colonel Francisco Moscoso y Lara | 1866-1871 |
| Colonel Luis de Ybanez y Garcia | 1871-1873 |
| Lieutenant Colonel Eduardo Beaumont y Calafat | 1873-1875 |
| Lieutenant Colonel Manuel Brabo y Barrera | 1875-1880 |
| Lieutenant Colonel Brochero y Parreno | 1880-1884 |
| Colonel Angel de Pazos Vela-Hidalgo | 1884-1884 |
| Captain Antonio Borreda | 1884-1884 |
| Lieutenant Colonel Francisco Olive y Garcia | 1884-1887 |
| Lieutenant Colonel Enrique Solano | 1887-1890 |
| Lieutenant Colonel Joaquin Vara de Rey | 1890-1891 |
| Lieutenant Colonel Luis Santos | 1891-1892 |
| Lieutenant Colonel Vicente Gomez Hernandez | 1892-1893 |
| Lieutenant Colonel Emilio Galisteo Brunenque | 1893-1895 |
| Lieutenant Colonel Don Jacobo Marina | 1895-1897 |
| Lieutenant Colonel Don Juan Marina | 1897-1898 |